Nonhygroscopic selenide of Ge0.35Ga0.05Se 0.60 was introduced into the Li2S-P2S 5 system by partially substituting P2S5 to form a new lithium ion solid electrolyte. And the electrochemical property of the as-prepared solid electrolyte was systematically studied. The optimal sample achieved a wide electrochemical window over 6.5 V and fairly high Li-ion conductivity of 1.5 × 10-3 S cm-1 at ambient temperature. And it is also verified that the studied electrolyte was much stable when contacts with lithium metal at 100 °C for 4 h. This new finding may provide an electrolyte material for developing all-solid-state lithium batteries. © 2014 Published by Elsevier B.V.