Both optical and scanning electron microscopy (SEM) showed spherical microcapsules with irregular topography due to the presence of holes on its surface. The obtained size distribution range was modified when the stirring rate was increased. At 400 rpm, bimodal behavior was observed in the range of 20–420 _m; at 800 and 1200 rpm, the behavior became unimodal and the range was from 20 to 200 _m and 20 to 160 _m, respectively.