Surfaces with special wetting properties have been attracting world-wide scientific interests in recent years due to their desirable practical applications.1–6 A surface is considered to be superoleophobic (SOP) if the apparent contact angle h*for a contacting low surface tension oil droplet is greater than 150.7 While a few SOP surfaces have been previously engineered,8–10 there are very few stimuli-responsive SOP surfaces reported displaying switch-able oil wetting properties 11,12 and even significantly fewer 13,14 functioning as a both SOP and superhydrophilic(hwater 0) coating in air. In this work, we have fabricated remarkably durable smart surfaces that, for the first time,exhibit clever solvent-responsiveness of extreme wetting behaviors that display both superoleophobicity with a widesurface tension range of non polar oils and quick switch to counterintuitive superwettability with virtually all the contacting polar liquids. Our smart surfaces, allowing nonpolar oil liquids, even for ultra-low surface tension gasoline, such as hexane (18.5 mN m21) and heptane (20.6 mN m21), toeasily bead up on the surface with a robust extreme oil-