Sodiumchloride, calcium chloride, potassium acetate, calcium nitrate and a mixture of sodium and potassium acetates wereadded to the synthetic charges and the results were compared to the experiments already done without the presenceof the salts, revealing the ethanol enrichment in the top product of the distillation unit, for all the systems analyzed.Another charge from the refinery, known as load of wine without yeast, was evaluated and the results indicated thesame behavior, enriching the ethanol with the application of the saline extractive distillation.