Chemical shifts and full widths at half maximum intensity (FWHM) of KD and KE1,3 x-ray emission lines and differences of full widths at half maximum intensity ('FHWM) using metallic element as reference for these emission lines were measured for oxygen compounds of elements in the range 22 d Z d 29 with a Wavelength-Dispersive X-Ray Fluorescence spectrometry (WDXRF). It was also found larger chemical shifts and FWHM for KE1,3 lines than those of KD ones. It should be noted that the magnitude of chemical shifts increases with increase in the numbers of ligand atom. Keyword: Chemical shifts, ligand atom, FWHM
© 2015 The Authors. Published by Elsevier Ltd. Peer-review under responsibility of Istanbul University.
Keywords: Chemical shifts; ligand atom; FWHM;