The first part of this study examined the effect of operating conditions on Fenton pretreatment of an antibiotic wastewater containing amoxicillin and cloxacillin. The optimum H202/COD and H2o2/Fe2+ molar ratios were 2.5 and 20, respectively. Under the optimum operating conditions, complete degradation of the antibiotics occurred in 1 min. In the second part of this study, a bench-scale SBR was operated for 239 days and fed
with Fenton-treated wastewater under different operating conditions. BOD5/COD ratio below 0.40 of the Fentontreated wastewater had negative effect on the SBR performance. Hydraulic retention time (HRT) of 12 h was found suitable for the SBR and increasing HRT to 24 and 48 h did not signifi cantly improve theSBR efficiency. Statistical analysis (two-way ANOVA) was made on the results to optimize the H2O2/Fe2+ molar ratio and Fenton reaction time and it was found possible to reduce the Fe2+ dose and increase the Fenton reaction time. Under the best operating conditions (H
2O2/COD molar ratio 2.5, H2O2/Fe2+ molar ratio 150, Fenton reaction time 120 min and HRT 12 h), the combined Fenton-SBR process efficiency was 89% for sCOD removal and the SBR effuent met the discharge standards. Combined Fenton-SBR is a feasible process for antibiotic wastewater treatment.
The first part of this study examined the effect of operating conditions on Fenton pretreatment of an antibiotic wastewater containing amoxicillin and cloxacillin. The optimum H202/COD and H2o2/Fe2+ molar ratios were 2.5 and 20, respectively. Under the optimum operating conditions, complete degradation of the antibiotics occurred in 1 min. In the second part of this study, a bench-scale SBR was operated for 239 days and fed
with Fenton-treated wastewater under different operating conditions. BOD5/COD ratio below 0.40 of the Fentontreated wastewater had negative effect on the SBR performance. Hydraulic retention time (HRT) of 12 h was found suitable for the SBR and increasing HRT to 24 and 48 h did not signifi cantly improve theSBR efficiency. Statistical analysis (two-way ANOVA) was made on the results to optimize the H2O2/Fe2+ molar ratio and Fenton reaction time and it was found possible to reduce the Fe2+ dose and increase the Fenton reaction time. Under the best operating conditions (H
2O2/COD molar ratio 2.5, H2O2/Fe2+ molar ratio 150, Fenton reaction time 120 min and HRT 12 h), the combined Fenton-SBR process efficiency was 89% for sCOD removal and the SBR effuent met the discharge standards. Combined Fenton-SBR is a feasible process for antibiotic wastewater treatment.
การแปล กรุณารอสักครู่..