Application of activated carbon prepared from Pomegranate wood modified with 1-(2-fluorobenzoyl)-3-{3-
[3-(2-fluorobenzoy)-thioureido]-phenyl}-thiourea for the rapid removal of toxic metal ion impurities was
investigated. The impact of several parameters, like ion concentration, pH, contact time, adsorbent dosage, and
temperature was elucidated and optimization was carried out using of bee algorithm superimposed with
response surface methodology, the obtained optimum experimental conditions for the parameters i.e. ion concentration,
pH, contact time, adsorbent dosage, and temperature are 28.6mg L−1, 5.6, 70min, 1.6 g, and 36.1 °C respectively.
The experimental isotherm data reveals the suitability and applicability of the Langmuir isothermmodel
(R2= 0. 997) and kinetic data was found to be in good agreement with the pseudo second-order equation (R2=
0.9961) model. Thermodynamic parameter studies i.e.ΔGnegative reveal the feasibility, and positiveΔHvalues confirm
the endothermicity of the process.
Application of activated carbon prepared from Pomegranate wood modified with 1-(2-fluorobenzoyl)-3-{3-[3-(2-fluorobenzoy)-thioureido]-phenyl}-thiourea for the rapid removal of toxic metal ion impurities wasinvestigated. The impact of several parameters, like ion concentration, pH, contact time, adsorbent dosage, andtemperature was elucidated and optimization was carried out using of bee algorithm superimposed withresponse surface methodology, the obtained optimum experimental conditions for the parameters i.e. ion concentration,pH, contact time, adsorbent dosage, and temperature are 28.6mg L−1, 5.6, 70min, 1.6 g, and 36.1 °C respectively.The experimental isotherm data reveals the suitability and applicability of the Langmuir isothermmodel(R2= 0. 997) and kinetic data was found to be in good agreement with the pseudo second-order equation (R2=0.9961) model. Thermodynamic parameter studies i.e.ΔGnegative reveal the feasibility, and positiveΔHvalues confirmthe endothermicity of the process.
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