Currently, bioethanol research is still continuously expanding. Not only serve as a renewable energy, bioethanol that is believed as most prospective bioenergy, can also be a solution for air pollution problem. While production of first generation ethanol from starchy materials has developed well, production process of second generation ethanol from lignocellulosic materials is still looking for its economical feasibility. Furthermore, first generation ethanol materials are also generally very important food sources that will impair food security issue and their availability are also not sufficient to cover the total required bioethanol production. Therefore, this research aims to elaborate lignocellulosic ethanol production prospective from sugarcane bagasse as an effort to overcome bottleneck of lignocellulosic ethanol.