Materials and methods 2.1.Synthesis

Materials and methods
2.1.Synthesis of PCs and NPstrapping ThePCswerefabricatedbytheLbLtechnique,usingalternate depositionofpositiveandnegativepolyelectrolytepolymerlayers onsacrificialcores[40,41].Aspolyelectrolytes,poly(sodium4styrenesulfonate)(PSS,Mw=70,000g/mol,Sigma-Aldrich #243051)andpoly(allylamine)hydrochloride(PAH,Mw=5 8,000g/mol,Sigma-Aldrich,#283223)wereusedasweakpolyanion andpolycation,respectively.2mg/mLpolymersolutionswerepreparedwith0.5MNaCl(CarlRoth,#HN00.2)concentrationand adjustedtopH6.5with50mMNaOH(CarlRoth,#6771.1)and 50mMHCl(CarlRoth,#7476.1)solutions. SacrificialCaCO3coreswereproducedbymixing615lLof 0.33MCaCl2(Sigma-Aldrich,#223506),615lLof0.33MNa2CO3 (Sigma-Aldrich,#S7795),and770lLmilliQwaterundervigorous stirringfor30satroomtemperature.Thereactionwaskeptwithoutstirringfor4furtherminutes,andthecoreswerethenprecipitatedbycentrifugationat800relativecentrifugalforce(rcf)for 10s.Thesamplewasresuspendedin1mLmilliQwater.Thisprocedurewasrepeated4times,andthenthecoresweredried.For LbLcoatingthedriedcoresweremixedwith1mLof2mg/mL PSSin0.5MNaClsolution,sonicatedfor2min,andstirredfor 10min.ToremovetheexcessofPSS,thesamplewaswashedby precipitationat800rcf(10s;3washes).ForadditionofaPAHshell thenowPSScoatedsamplewasthenresuspendedin1mLof2mg/ mLPAHina0.5MNaClsolution,andthewashingprocedurewas repeated.Aftertheadditionofanextrabilayer(1PSSand1PAH) followingthesamedepositionsstepsthecoatedcoresweremodif iedwithIONPs(seedetailsaboutsynthesis[42],surfacecoating [43],andconcentrationcalculationoftheIONPsinthesupporting information).400lLof0.4lMIONPsinmilliQwaterwereadded

ผลลัพธ์ (ไทย) 1:

วัสดุและวิธีการ 2.1.Synthesis ชิ้นและ NPstrapping ThePCswerefabricatedbytheLbLtechnique, usingalternate depositionofpositiveandnegativepolyelectrolytepolymerlayers onsacrificialcores [40,41] Aspolyelectrolytes,poly(sodium4styrenesulfonate) (PSS, Mw = 70, 000 กรัม/โมล 243051 # Sigma Aldrich) ไฮโดรคลอไรด์ andpoly (allylamine) (ผา Mw = 5 8, 000 กรัม/โมล Sigma Aldrich, #283223) wereusedasweakpolyanion andpolycation,respectively.2mg/mLpolymersolutionswerepreparedwith0.5MNaCl (CarlRoth, #HN00.2) concentrationand adjustedtopH6.5with50mMNaOH (CarlRoth, #6771.1) และ 50mMHCl (CarlRoth, #7476.1) โซลูชั่น SacrificialCaCO3coreswereproducedbymixing615lLof 0.33MCaCl2 (ซิก-Aldrich, #223506), 615lLof0.33MNa2CO3 (ซิก-Aldrich, #S7795), and770lLmilliQwaterundervigorous stirringfor30satroomtemperature Thereactionwaskeptwithoutstirringfor4furtherminutes, andthecoreswerethenprecipitatedbycentrifugationat800relativecentrifugalforce (rcf) สำหรับ 10s Thesamplewasresuspendedin1mLmilliQwater.Thisprocedurewasrepeated4times,andthenthecoresweredried สำหรับ LbLcoatingthedriedcoresweremixedwith1mLof2mg/mL PSSin0.5MNaClsolution, sonicatedfor2min, andstirredfor 10 นาที ToremovetheexcessofPSS, thesamplewaswashedby precipitationat800rcf(10s;3washes) ForadditionofaPAHshell thenowPSScoatedsamplewasthenresuspendedin1mLof2mg / mLPAHina0.5MNaClsolution, andthewashingprocedurewas ที่ซ้ำกัน Aftertheadditionofanextrabilayer(1PSSand1PAH) followingthesamedepositionsstepsthecoatedcoresweremodif iedwithIONPs(seedetailsaboutsynthesis[42],surfacecoating [43],andconcentrationcalculationoftheIONPsinthesupporting information).400lLof0.4lMIONPsinmilliQwaterwereadded

ผลลัพธ์ (ไทย) 2:

วัสดุและวิธีการ
2.1.Synthesis ของเครื่องคอมพิวเตอร์และ NPstrapping ThePCswerefabricatedbytheLbLtechnique, depositionofpositiveandnegativepolyelectrolytepolymerlayers usingalternate onsacrificialcores [40,41] .Aspolyelectrolytes โพลี (sodium4styrenesulfonate) (PSS, Mw = 70,000g / mol, Sigma-Aldrich # 243051) andpoly (allylamine) ไฮโดรคลอไร (PAH , Mw = 5 8,000g / mol, Sigma-Aldrich, # 283223) wereusedasweakpolyanion andpolycation, respectively.2mg / mLpolymersolutionswerepreparedwith0.5MNaCl (CarlRoth # HN00.2) concentrationand adjustedtopH6.5with50mMNaOH (CarlRoth # 6,771.1) และ 50mMHCl (CarlRoth # 7,476.1) โซลูชั่น SacrificialCaCO3coreswereproducedbymixing615lLof 0.33MCaCl2 (Sigma-Aldrich, # 223506) 615lLof0.33MNa2CO3 (Sigma-Aldrich # S7795) and770lLmilliQwaterundervigorous stirringfor30satroomtemperature.Thereactionwaskeptwithoutstirringfor4furtherminutes, andthecoreswerethenprecipitatedbycentrifugationat800relativecentrifugalforce (RCF) สำหรับ 10s.Thesamplewasresuspendedin1mLmilliQwater.Thisprocedurewasrepeated4times, andthenthecoresweredried.For LbLcoatingthedriedcoresweremixedwith1mLof2mg / mL PSSin0.5MNaClsolution, sonicatedfor2min, andstirredfor 10min.ToremovetheexcessofPSS, precipitationat800rcf thesamplewaswashedby (10s; 3washes) .ForadditionofaPAHshell thenowPSScoatedsamplewasthenresuspendedin1mLof2mg / mLPAHina0.5MNaClsolution, andthewashingprocedurewas repeated.Aftertheadditionofanextrabilayer (1PSSand1PAH) followingthesamedepositionsstepsthecoatedcoresweremodif iedwithIONPs (seedetailsaboutsynthesis [42] surfacecoating [43] ข้อมูล andconcentrationcalculationoftheIONPsinthesupporting) .400lLof0.4lMIONPsinmilliQwaterwereadded

ผลลัพธ์ (ไทย) 3:

วัสดุและวิธีการ2.1.synthesis ของพีซี และ npstrapping thepcswerefabricatedbythelbltechnique usingalternate depositionofpositiveandnegativepolyelectrolytepolymerlayers , onsacrificialcores [ 40,41 ] aspolyelectrolytes โพลี ( sodium4styrenesulfonate ( แฮ่ ) , 70000g MW = / โมล ซิกม่า Aldrich # 243051 ) andpoly ( อัลลิลามีนไฮโดรคลอไรด์ ( ป่า ) 3 = 5 8000g / โมล ซิกม่า Aldrich # 283223 ) wereusedasweakpolyanion andpolycation Nicotinell / mlpolymersolutionswerepreparedwith0.5mnacl ( ตามลำดับ ) carlroth # , hn00.2 ) concentrationand adjustedtoph6.5with50mmnaoh ( carlroth # , 6771.1 ) และ 50mmhcl ( carlroth # , 7476.1 ) โซลูชั่น sacrificialcaco3coreswereproducedbymixing615llof 0.33mcacl2 ( ซิกม่า Aldrich # 223506 ) 615llof0.33mna2co3 ( ซิกม่า Aldrich # s7795 ) and770llmilliqwaterundervigorous stirringfor30satroomtemperature . thereactionwaskeptwithoutstirringfor4furtherminutes andthecoreswerethenprecipitatedbycentrifugationat800relativecentrifugalforce , ( rcf ) เป็นเวลา thesamplewasresuspendedin1mlmilliqwater . thisprocedurewasrepeated4times andthenthecoresweredried.for , lblcoatingthedriedcoresweremixedwith1mlof2mg / ml pssin0.5mnaclsolution sonicatedfor2min andstirredfor , , วัน . toremovetheexcessofpss thesamplewaswashedby , precipitationat800rcf ( 10s ; 3washes ) foradditionofapahshell thenowpsscoatedsamplewasthenresuspendedin1mlof2mg / mlpahina0.5mnaclsolution andthewashingprocedurewas repeate , d.aftertheadditionofanextrabilayer ( 1pssand1pah ) followingthesamedepositionsstepsthecoatedcoresweremodif iedwithionps ( seedetailsaboutsynthesis [ 42 ] , เซอร์เฟซ โคทติ้ง [ 43 ] andconcentrationcalculationoftheionpsinthesupporting 400llof0.4lmionpsinmilliqwaterwereadded ข้อมูล )