หน้า 1 จาก 7NS-3 Version 2.0 Effective Date 05.10.2011 Material Safety Data Sheet 1/7 Print Date 06.10.2011 000000024717 MSDS_TH 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING Material Name : NS-3 Uses : Transmission oil. Product Code : 001E1692 Manufacturer/Supplier : The Shell Company of Thailand Ltd Klongtoey 10 Soonthornkosa Road Bangkok 10110 Thailand Telephone : (+66) 26579888 Fax : (+66) 26579609 Emergency Telephone Number : 0-2262-7333 2. COMPOSITION/INFORMATION ON INGREDIENTS Preparation Description : Synthetic base oil and additives. Highly refined mineral oil. Additional Information : The highly refined mineral oil contains <3% (w/w) DMSO- extract, according to IP346. The highly refined mineral oil is only present as additive diluent. 3. HAZARDS IDENTIFICATION EC Classification : Not classified as dangerous under EC criteria. Health Hazards : Not expected to be a health hazard when used under normal conditions. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Used oil may contain harmful impurities. Signs and Symptoms : Oil acne/folliculitis signs and symptoms may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Not classified as dangerous for the environment. 4. FIRST AID MEASURES General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If symptoms persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent หน้า 1 จาก 7หน้า 2 จาก 7NS-3 Version 2.0 Effective Date 05.10.2011 Material Safety Data Sheet 2/7 Print Date 06.10.2011 000000024717 MSDS_TH irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Advice to Physician : Treat symptomatically. 5. FIRE FIGHTING MEASURES Clear fire area of all non-emergency personnel. Specific Hazards : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Suitable Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media : Do not use water in a jet. Protective Equipment for Firefighters : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 6. ACCIDENTAL RELEASE MEASURES Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. See Chapter 13 for information on disposal. Observe the relevant local and international regulations. Protective measures : Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Clean Up Methods : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Storage : Keep container tightly closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Storage หน้า 2 จาก 7หน้า 3 จาก 7NS-3 Version 2.0 Effective Date 05.10.2011 Material Safety Data Sheet 3/7 Print Date 06.10.2011 000000024717 MSDS_TH Temperature: 0 - 50 °C / 32 - 122 °F Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this document, it is provided for information only. Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Oil mist, mineral ACGIH TWA [Inhalable fraction.] 5 mg/m3 Exposure Controls : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapours [boiling point >65°C(149 °F)]. Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. หน้า 3 จาก 7หน้า 4 จาก 7NS-3 Version 2.0 Effective Date 05.10.2011 Material Safety Data Sheet 4/7 Print Date 06.10.2011 000000024717 MSDS_TH Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Protective Clothing : Skin protection not ordinarily required beyond standard issue work clothes. Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Environmental Exposure Controls : Minimise release to the environment. An environmental assessment must be made to ensure compliance with local environmental legislation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Green. Liquid at room temperature. Odour : Slight hydrocarbon. pH : Not applicable. Initial Boiling Point and Boiling Range : > 280 °C / 536 °F estimated value(s) Pour point : Data not available Flash point : Typical 170 °C / 338 °F (COC) Upper / lower Flammability or Explosion limits : Typical 1 - 10 %(V) Auto-ignition temperature : > 320 °C / 608 °F Vapour pressure : < 0.5 Pa at 20 °C / 68 °F (estimated value(s)) Density : Typical 840 kg/m3 at 15 °C / 59 °F Water solubility : Negligible. Solubility in other solvents : Data not available n-octanol/water partition coefficient (log Pow) : > 6 (based on information on similar products) Dynamic viscosity : Data not available Kinematic viscosity : Typical 25 mm2/s at 40 °C / 104 °F Vapour density (air=1) : > 1 (estimated value(s)) Evaporation rate (nBuAc=1) : Data not available 10. STABILITY AND REACTIVITY Stability : Stable. Conditions to Avoid : Extremes of temperature and direct sunlight. Materials to Avoid : Strong oxidising agents. Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. 11. TOXICOLOGICAL INFORMATION Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Acute Oral Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rat Acute Dermal Toxicity : Expected to be of low toxicity: LD50 > 5000 mg/kg , Rabbit Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Skin Irritation : Expected to be slightly irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Ey
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