Natural hemp fabric reinforced epoxy resin composites were prepared in flame retarded form. Fabrics
were treated in three ways: the first method involved the immersion of preheated fabric into cold
phosphoric acid solution (allowing penetration into the capillaries of the fibres) and subsequent
neutralization, the second way was a reactive modification carried out with an aminosilane-type
coupling agent, while the third treatment combined the solegel surface coating with the first method.
The introduction of phosphorus into the reinforcing fibres decreased the flammability not only of the
hemp fabrics, but also of the epoxy composites made thereof. By applying amine-type phosphoruscontaining
curing agent (TEDAP) in combination with the treated fabrics, V-0 UL-94 rating was achieved.
Composites of unexpectedly improved static and dynamic mechanical properties could be prepared only
when the simple phosphorous fibre treatment and reactive flame retardancy was combined.