When you have a need to set a PSV on a vessel and you don't have its MAWP figure, you can employ the "design" pressure value - as long as it can be proven that the vessel is in as good a physical condition as the day it was fabricated. Note that I'm going to lengths to define the physical condition of the vessel. We often neglect to mention that we are ASSUMING that the physical condition of the vessel doesn't change from the day it was fabricated. This can be a dangerous assumption that doesn't necessarily apply. A vessel can undergo corrosion and wear as well as other chemical attacks through its use and lifetime. Physical and meticulous inspections and reports are essential to ensure that the vessel can be safely applied to a process --- especially to a high-pressure application. And I consider any pressure over 50 psig as HIGH PRESSURE. When a vessel explodes, it isn't the pressure that kills you; it's the amount of shrapnel and steel pieces that are blown about that do the damage. And even 50 psig can cause a considerable amount of serious damage if allowed to trigger a vessel failure.