The polymer polyethylene glycol (PEG) is a water-soluble, low toxicity, and flexible polymer and has some unique properties that support its selection as the second polymer in the preparation of polymer blend with PVA. PEG has good chemical and physical properties[PVA-PEG ]; thus, it can be used in many industrial applications and also used as a binder in the preparation of technical ceramics. It may be also emphasized that the monomer unit of PEG Thus, PEG is more attractive towards polymer PVA due to the presence of the hydroxyl group (OH) in the side chain, which controls the desirable physiochemical properties of the blend within the compositional regime