of the complexes in DM systems spectra the of the oxidovanadium of d the easiest spectra e are the 267 the although interpretation electronic Unfortunately, (1-4) complexes expe Solution to transitions. use been complicated by the deviation of the complexes has from regular octahedral stereochemistry[24]. Three bands are normally observed around 485, 460 and 430 case of the phenolic complexes(1) and(4). On a simple crystal field model, these bands would be inter- preted as the transitions from the B ground term to the 2E, 2Bu and 2Ar terms[24], respectively. However, such a treatment does not give a good quantitative fit to the spectra and the axial T- bonding must be taken into account In case of the oxinato(2) and Phen(3)