For intercalate Co(salen)0.70Mn0.65PS3·H2O (D) it only
exhibits the paramagnetism in the range of the measured temperature
(1.8–300K in Fig. 10). The M–H curve further confirms
that [Co(salen)0.70Mn0.65PS3·H2O (D) is a paramagnet. Due
to the existence of much more intralayered Mn2+ vacancies
of the host layer in it the dilution of the Mn2+ ion vacancies
is much stronger than that of other related intercalation
compounds such as [Mn(salen)]0.26Mn0.87PS3·0.5H2O and
[Fe(salen)]0.56Mn0.72PS3·0.75H2O. Therefore, the dilution of
theMn2+ ion vacancies can drastically alter the magnetic properties
of the intercalation compound and make an antiferromagnet
of MnPS3 become a paramagnet after intercalation. Similar
to the above intercalation compounds [Mn(salen)]0.26Mn0.87
PS3·0.25H2O and [Fe(salen)]0.56Mn0.72PS3·0.75H2O it does
not show spin crossover property.