In this study near infrared hyperspectral imaging (NIR-HSI) is used to provide a fast, non-contact, non-
invasive and non-destructive method for the analysis of explosive residues on human handprints.
Volunteers manipulated individually each of these explosives and after deposited their handprints on
plastic sheets. For this purpose, classical explosives, potentially used as part of improvised explosive
devices (IEDs) as ammonium nitrate, blackpowder, single- and double-base smokeless gunpowders and
dynamite were studied. A partial-least squares discriminant analysis (PLS-DA) model was built to detect
and classify the presence of explosive residues in handprints. High levels of sensitivity and specificity for
the PLS-DA classification model created to identify ammonium nitrate, blackpowder, single- and double-
base smokeless gunpowders and dynamite residues were obtained, allowing the development of a
preliminary library and facilitating the direct and in situ detection of explosives by NIR-HSI.
Consequently, this technique is showed as a promising forensic tool for the detection of explosive
residues and other related samples.