In a present paper the results of pure metallic silver electrochemical recovery from the solution
obtained by two-steps of chloride leaching process of Lubin, Poland copper flotation concentrate are
discussed. Potential-controlled electrolysis (PCEl) was used as a promising method of silver
electrochemical recovery from low concentration complex composition aqueous solutions. The studied
solution contained approximately 50 mg/L of silver. The electroreduction of silver was studied using
cyclic voltammetry and chronoamperometry in two and three electrode configuration systems. The
effect of several factors such as potential, time of electrolysis on selectivity of silver reduction was
studied. Based upon conducted experiments the conditions of pure silver powders cathodic
electrodeposition using PCEl method were determined.