Cement kiln dust (CKD)–sludge–silica fume pastes were hydrothermally hardened at a pressure of 8 atm
of saturated steam for different autoclaving ages. Hydration characteristics of the autoclaved CKD–
sludge–silica fume pastes were studied by the determination of compressive strength and chemically
combined water contents at different autoclaving ages. The phase composition and morphology of the
formed hydrates were studied using X-ray diffraction analysis (XRD) and scanning electron microscopy
(SEM). The replacement of silica fume in CKD–sludge mixtures results in a marked increase in strength
values of the autoclaved specimens at all stages of the hydrothermal process. The results of X-ray diffraction
analysis and SEM-micrographs of autoclaved specimens for various mixtures indicates that the main
hydration products identified are calcium silicate hydrates and minor amounts of CaCO3.