Why is this? There are two reasons: First, although the concentrations of these gases are not nearly as large as that of oxygen and nitrogen (the main constituents of the atmosphere), neither oxygen or nitrogen are greenhouse gases. This is because neither has more than two atoms per molecule (i.e. their molecular forms are O2 and N2, respectively), and so they lack the internal vibrational modes that molecules with more than two atoms have. Both water and CO2, for example, have these "internal vibrational modes", and these vibrational modes can absorb and reradiate infrared radiation, which causes the greenhouse effect