The nonoxidative phase of the pathway begins with the conversion of ribulose5-phosphate to ribose-5-phosphate by ribulose-5-phosphate isomerase or to xylulose-5-phosphate by ribulose-5-phosphate epimerase. During the remaining reactions of the pathway (Figure 8.14b), transketolase and transaldolase catalyze the interconversions of trioses, pentoses, and hexoses. Transketolase is a TPPrequiring enzyme that transfers two-carbon units from a ketose to an aldose. (TPP, thiamine pyrophosphate, is the coenzyme form of thiamine, also known as vitamin