Crystallographic and phase structures of the thin films were determined by X-ray diffraction (Bruker AXS-8D;
Bruker Corporation, Billerica, MA, USA) with CuKα radiation (λ= 0.1541 nm) in the scanning range was between 2θ= 25° and 2θ= 55°. The optical properties of the deposited films was measured in the range of 300 to 800 nm using by an
ultraviolet-visible spectrophotometer (UV, Lambda 35; PerkinElmer Inc.,