Poly(2,6-dimethyl-1,4-phenyleneoxid

Poly(2,6-dimethyl-1,4-phenyleneoxide)(PPO)wasbrominatedundertheconditionsofradicalmechan-
ism andsubsequentlyquaternizedwithtrimethylamine.Flatmembraneswerepreparedbycasting
quaternizedPPO(qPPO)dissolvedinethanolorethanol/dimethylformamidemixtureonaTeflon plate
followedbysolventevaporation.Themembraneswerecharacterizedbytheirdegreeofswellingin
water,ionexchangecapacities(IEC)andionicconductivities.qPPOwithadegreeofquaternizationof
25.5 mol%andwithanionicconductivitiesof10.09S/mand12.34S/m(at50 1C and70 1C, respectively)
wastestedasananion-conductivepolymerbinderinasinglecellalkalinelaboratoryelectrolyzerin
which theanodeandcathodecompartmentswereseparatedwithaheterogeneousanionselective
membrane. ThecathodecontainedPt/carboncatalystbondedwithqPPOsothatPt/qPPOweightratio
was85/15.TheanodecontainedNiCo2O4 spinel catalystwhichwasbondedeitherwithqPPO(spinel/
qPPO weightratios95/5,90/10or75/25)orwithanon-conductingPTFE(spinel/PTFEweightratio85/
15).ItwasfoundthattheapplicationoftheqPPObinderintheanodeleadtohighercurrentdensities
than theapplicationofanon-conductivePTFEbinderatallelectrolyteKOHconcentrations(1–15wt%).
The performanceofalaboratorymembraneelectrolyzerwiththeanodecontainingNiCo2O4 spinel
catalystbondedwithqPPO(spinel/qPPOweightratio75/25)anda1wt%KOHelectrolytewassimilarto
that ofanindustryunitwitha30wt%KOHelectrolyte

ผลลัพธ์ (ไทย) 2:

โพลี (2,6-dimethyl-1,4-phenyleneoxide) (PPO) wasbrominatedundertheconditionsofradicalmechan-
ลัทธิ mol% andwithanionicconductivitiesof10.09S / mand12.34S / m (at50 1C and70 1C, theanodeandcathodecompartmentswereseparatedwithaheterogeneousanionselective เมมเบรน นิล catalystwhichwasbondedeitherwithqPPO (นิล / qPPO theapplicationofanon-conductivePTFEbinderatallelectrolyteKOHconcentrations (1-15wt%). นิล performanceofalaboratorymembraneelectrolyzerwiththeanodecontainingNiCo2O4 catalystbondedwithqPPO (นิล / qPPOweightratio75 / 25) anda1wt% KOHelectrolytewassimilarto ที่ ofanindustryunitwitha30wt% KOHelectrolyte

ผลลัพธ์ (ไทย) 3:

พอลิ 2,6-dimethyl-1,4-phenyleneoxide ) ( PPO ) wasbrominatedundertheconditionsofradicalmechan -
ลัทธิ andsubsequentlyquaternizedwithtrimethylamine . flatmembraneswerepreparedbycasting
quaternizedppo ( qppo ) dissolvedinethanolorethanol / dimethylformamidemixtureonateflon จาน

followedbysolventevaporation . themembraneswerecharacterizedbytheirdegreeofswellingin น้ำionexchangecapacities ( IEC ) andionicconductivities . qppowithadegreeofquaternizationof
25.5 โมล % andwithanionicconductivitiesof10.09s / mand12.34s / m ( at50 1C and70 1c ตามลำดับ ) ซึ่ง theanodeandcathodecompartmentswereseparatedwithaheterogeneousanionselective


wastestedasananion conductivepolymerbinderinasinglecellalkalinelaboratoryelectrolyzerin เมมเบรนthecathodecontainedpt / carboncatalystbondedwithqpposothatpt / qppoweightratio
85 / 15.theanodecontainednico2o4 catalystwhichwasbondedeitherwithqppo สปิเนล ( spinel /
qppo weightratios95 / 5,90 / 10or75 / 25 ) orwithanon conductingptfe ( นิล / ptfeweightratio85 / 15 itwasfoundthattheapplicationoftheqppobinderintheanodeleadtohighercurrentdensities

)กว่า theapplicationofanon conductiveptfebinderatallelectrolytekohconcentrations ( 1 ) 15wt % )

catalystbondedwithqppo performanceofalaboratorymembraneelectrolyzerwiththeanodecontainingnico2o4 สปิเนล ( spinel / qppoweightratio75 / 25 ) anda1wt % kohelectrolytewassimilarto
ที่ ofanindustryunitwitha30wt % kohelectrolyte