A hydrometallurgical method was employed for recycling waste pharmaceutical blisters (WPBs);
leaching WPBs using hydrochloric acid solutions was conducted to separate aluminum from polyvinyl
chloride (PVC) plastic. The effects of temperature, hydrochloric acid concentration, reaction time, liquid/
solid ratio and agitation on leaching behavior were investigated under fixed conditions, and the recovery
of aluminum increases with an increase of the factors. Kinetic mechanism demonstrates leaching
aluminum is controlled by chemical reaction control model, and the activation energy of leaching
aluminum from WPBs is 87.24 kJ mol1. Under optimal conditions, the recovery of aluminum is up to
100%, implying complete separation of aluminum and PVC is achieved. The purified PVC plastic was
identified by Fourier transform infrared spectroscopy. A flowsheet of recycling WPBs by hydrometallurgical
method was designed, and economic analysis confirms the feasibility of recycling of WPBs using
hydrometallurgical method that is a relatively environmentally friendly technique.
© 2015 Elsevier Ltd. All rights reserved
A hydrometallurgical method was employed for recycling waste pharmaceutical blisters (WPBs);leaching WPBs using hydrochloric acid solutions was conducted to separate aluminum from polyvinylchloride (PVC) plastic. The effects of temperature, hydrochloric acid concentration, reaction time, liquid/solid ratio and agitation on leaching behavior were investigated under fixed conditions, and the recoveryof aluminum increases with an increase of the factors. Kinetic mechanism demonstrates leachingaluminum is controlled by chemical reaction control model, and the activation energy of leachingaluminum from WPBs is 87.24 kJ mol1. Under optimal conditions, the recovery of aluminum is up to100%, implying complete separation of aluminum and PVC is achieved. The purified PVC plastic wasidentified by Fourier transform infrared spectroscopy. A flowsheet of recycling WPBs by hydrometallurgicalmethod was designed, and economic analysis confirms the feasibility of recycling of WPBs usinghydrometallurgical method that is a relatively environmentally friendly technique.© 2015 Elsevier Ltd. All rights reserved
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