Wine is known to have a complex matrix and many studies in the literature report the determination of metals in wine [5]. Atomic and mass spectrometric techniques, such as flame atomic absorption spectrometry (F AAS), graphite furnace atomic absorp- tion spectrometry (GF AAS), inductively coupled plasma optical emission spectrometry (ICP OES) and inductively coupled plasma mass spectrometry (ICP-MS) are most frequently used for the wine analysis. The principal advantages of the AAS techniques are the high sensitivity in the case of GF AAS and simplicity and low cost in the case of F AAS. The disadvantage of AAS techniques is that they are typically designed for the determination of just one element at-a-time [3–5,10]. The plasma techniques have the advantages of high sensitivity and multi-element determination, with the disadvantage that compromised conditions have to be used, which are not optimum for each element, and the higher cost, mostly in the case of ICP-MS [3–5,11].