Zinc(II) DBM, Monomeric Form. The method was very similar
to that for the nickel analogue (light-green form). Starting from zinc
acetate dihydrate (2.20 g, 10 mmol), 3.6 g (65%) of pale pearly diaqua
complex was prepared; its dehydration (mass loss of 6.9% compared
to 6.6% calculated from eq 2 for Zn) yielded the white final product.
Anal. Found: C, 70.2; H, 4.30. Calcd for [Zn(DBM)2] (C30H22O4Zn):
C, 70.4; H, 4.33. The compound was recrystallized from chlorobenzene.
Zinc(II) DBM, Monomeric Form. The method was very similar
to that for the nickel analogue (light-green form). Starting from zinc
acetate dihydrate (2.20 g, 10 mmol), 3.6 g (65%) of pale pearly diaqua
complex was prepared; its dehydration (mass loss of 6.9% compared
to 6.6% calculated from eq 2 for Zn) yielded the white final product.
Anal. Found: C, 70.2; H, 4.30. Calcd for [Zn(DBM)2] (C30H22O4Zn):
C, 70.4; H, 4.33. The compound was recrystallized from chlorobenzene.
การแปล กรุณารอสักครู่..
