Precipitation and complex formation titrations
A large number of coulometric titrations have been developed with the anodic
generation of silver(I) ions. The generator electrode consisting of a heavy silver wire
can be constructed and a cell of the type shown in Fig. 5.16 can be used. Endpoints
can be detected with adsorption indicators or by potentiometric method. Similar
titrations based upon the generation of mercury(I) ions at a mercury anode have been
described.