In past the structural and physical effect of alkali and alkaline oxide containing glasses have been studied by many authors [1], [2] and [3]. The barium containing glasses has great importance. The barium oxide glasses are suitable for sulphate bearing high level radioactive liquid waste [4]. These glasses are also suitable material for making barrier of plasma display ribs [5]. Barium contains glasses are used to make gamma ray shielding material [6] and [7]. Barium contained borosilicate glasses are used to make crown optical glasses [8]. Beside the optical and structural effect of barium, some author has also studied the effect of barium on electrical properties glass [9].