Most of materials show increase in their dimensions when encountering a thermal flux under constant pressure. However, some materials contract under heat and show negative thermal expansion. Besides, if a solid material shows different thermal properties along different directions, thermal expansion can be anisotropic. Especially, this phenomenon takes place in reinforced composites, in which the reinforcement has different thermal properties from those of the matrix. Polymers like epoxy, generally have higher CTE in comparison with fibres and metals. In polymers, CTE is divided into two parts, before and after glass transient temperature (Tg). Polymers and composites lose most of their mechanical properties after the glass transition temperature.