Mixing and pelletizing sewage sludge ash (SSA) or municipal solid waste (MSW) fly ash with CaCl2 and
treating these pellets in a rotary reactor at approximately 1000 °C lead to a significant decrease of the heavy
metal concentration.
Experiments were carried out in an indirectly-heated laboratory-scale rotary reactor. From SSA, after 10 min
at 1050 °C, more than 95% of Cu, Pb and Zn could be removed. The heavy metal removal from municipal solid
waste (MSW) fly ash proceeded more slowly and often less efficiently. After 45 min at 1050 °C, 95% Cd, 60%
Cu, 98% Pb and 80% Zn could be removed.
Thermodynamic equilibrium calculations for possible single reactions were carried out. It was found that SiO2,
a main component in sewage sludge ash, accelerates the formation of HCl and Cl2. CaO, which is contained in
CaO-bearing phases in MSW fly ash, decreases the rate of this reaction. Al2O3, also contained in MSW fly
ash-phases, leads to the formation of aluminates. Cd-aluminate can be affected by HCl and Cl2, leading to a
lower removal rate. Zn-aluminate can only be affected by Cl2; Cu-aluminate is stable under chlorination
conditions. I.e., Cu and Zn can easily be incorporated into the MSW fly ash matrix