This paper reports on the development and optical characterization of heavy metal oxide (HMO)-based transparent glasses in the chemical composition of 15PbO–40B 2 O 3 –(45−x) ZnO−x TM 2+ (=Mn 2+ or Ni 2+ or Co 2+ ) (where x=0.2, 0.5mol%). For these glasses both absorption and emission spectra have been measured, in order to understand their optical performances. The XRD profiles have confirmed their glassy nature and the FTIR spectral features have been analyzed. From the emission spectra, a bright green emission (538nm) from Mn 2+ -glasses, an intense red emission (670nm) from Ni 2+ and from Co 2+ (625nm) glasses have been noticed very clearly. Based on the UV-absorption spectra of these materials, both direct and indirect bond gaps have been computed. Apart from the spectral analysis, different physical properties of these glasses have also been carried out. Due to the presence of both PbO and ZnO, these glasses are found to be good moisture-resistant optical systems. Both optical and physical properties have been found to be more encouraging towards their use as novel luminescent optical materials.
This paper reports on the development and optical characterization of heavy metal oxide (HMO)-based transparent glasses in the chemical composition of 15PbO–40B 2 O 3 –(45−x) ZnO−x TM 2+ (=Mn 2+ or Ni 2+ or Co 2+ ) (where x=0.2, 0.5mol%). For these glasses both absorption and emission spectra have been measured, in order to understand their optical performances. The XRD profiles have confirmed their glassy nature and the FTIR spectral features have been analyzed. From the emission spectra, a bright green emission (538nm) from Mn 2+ -glasses, an intense red emission (670nm) from Ni 2+ and from Co 2+ (625nm) glasses have been noticed very clearly. Based on the UV-absorption spectra of these materials, both direct and indirect bond gaps have been computed. Apart from the spectral analysis, different physical properties of these glasses have also been carried out. Due to the presence of both PbO and ZnO, these glasses are found to be good moisture-resistant optical systems. Both optical and physical properties have been found to be more encouraging towards their use as novel luminescent optical materials.
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