gas-phase injections. For the limit-of-detection (LOD) experiments, 25–200 _L of analytical grade n-octane were pipet-ted into a custom-made 1 L volumetric flask. The mouth of the flask was sealed with a 24/40 septa and left overnight for the octane to volatilize. To prepare a different dilution, the octane in the flask was cleared by removing the septa seal and running the flask through a cycle of nitrogen purging, oven heating at 80 ◦C, and repurging with nitrogen. After letting the flask cool down to room temperature, the volume of octane corresponding to the desired concentration