This paper shows that several alpha-boron type compounds may be useful as high-temperature
semiconductors with decent carrier motilities, high electrical resistivity, good optical transparency,
good stability under high radiation bombardment, and possess high neutron capture cross-sections.
The most promising are B12O2, B12P2, and B12As2. Their relationship to alpha-boron, B13C2, and other
derivative crystals is explained. A study of their chemical and thermodynamic properties indicates how
single crystals useful for electronic devices can be grown.