V.C.M. 2as supported by a phD scholarship (SFH/BD/65673/2009) and C.I.M Martins was soported by a postdocttoral scholarship (SFRH/BPD/42015/2007) both scholarships were funded by Fundaca~o ara a Cência e Tecnologia (qren-oph-Avanced trainning,subsidized by the European social fund and national MED fund).