The maximum oxidative degradation rate (at +1.0 V) and electron exchange rate (species, MB+ to LMB at −0.7 V) were ∼78.2 × 10−3 min−1 and ∼8.3 × 107 L mol−1 s−1, respectively. Electrochemical bleaching of aromatic compounds like MB+ can potentially be executed through chemical oxidation processes followed by electrochemical approaches which might be adopted by the effluent treatment plants to degraded textile effluents with high percentage of dye-destruction.