heating cellulose fiber at higher temperatures than normal
drying conditions has been shown to appreciably reduce the hygroscopicity and the
subsequent swelling and shrinking of the lingo-cellulosic material. The thermal
modifications of wood result in changes of lignin and hemicelluloses that become less
hygroscopic, while the crystallinity of fiber increases. Rusche (1973) studied the
strength properties of dried wood fiber after thermal treatment. Wood fibers were
heated at temperature range 100 to 200°C. The decrease in the strength properties was
related to the rate of thermal degradation. The modulus of elasticity decreased
significantly only when the losses of substance caused by the thermal treatment.
Hakkou, Petrissana, Zoulalian, and Gerardin (2005) investigated
the change of wettability of wood during thermal treatment. Wood blocks were
thermal treatment in an oven at different temperature (20-240o
C) for 8 hrs. FTIR
results showed that thermal treatment led to an important decrease of the carbonyl
band at 1730 cm-1
indicating hemicelluloses degradation. The hydrophilic wood
became rather hydrophobic after thermal treatment in a range of temperatures
between 130 and 160o
C.
Saikia (2008) reported the effect of heat on the structural
characteristics of sisal fiber. X-ray diffraction and IR results showed that sisal fiber
had a cellulosic structure in nature. The cellulosic structure of the fiber was
unchanged on heating up to 177°C. TG, DTG, and DSC studies showed that three
distinct thermal processes occurred in the fiber under heating at temperature from
37°C to 487°C. The first step took place in a temperature range from approximate 17
37°C to 107°C due to a dehydration process. No decomposition of the fiber took place
up to about 227°C. The second thermal process of the sample was under heating in
the temperature above 227°C. Thermal decomposition led to incomplete
carbonization of the fibers. The original structural features of the cellulosic were not
completely lost in temperature above 227°C. The third thermal process was
representative of combustion of the fibers to carbonized material.
heating cellulose fiber at higher temperatures than normal drying conditions has been shown to appreciably reduce the hygroscopicity and the subsequent swelling and shrinking of the lingo-cellulosic material. The thermal modifications of wood result in changes of lignin and hemicelluloses that become less hygroscopic, while the crystallinity of fiber increases. Rusche (1973) studied the strength properties of dried wood fiber after thermal treatment. Wood fibers were heated at temperature range 100 to 200°C. The decrease in the strength properties was related to the rate of thermal degradation. The modulus of elasticity decreased significantly only when the losses of substance caused by the thermal treatment. Hakkou, Petrissana, Zoulalian, and Gerardin (2005) investigated the change of wettability of wood during thermal treatment. Wood blocks were thermal treatment in an oven at different temperature (20-240oC) for 8 hrs. FTIR results showed that thermal treatment led to an important decrease of the carbonyl band at 1730 cm-1 indicating hemicelluloses degradation. The hydrophilic wood became rather hydrophobic after thermal treatment in a range of temperatures between 130 and 160oC. Saikia (2008) reported the effect of heat on the structural characteristics of sisal fiber. X-ray diffraction and IR results showed that sisal fiber had a cellulosic structure in nature. The cellulosic structure of the fiber was unchanged on heating up to 177°C. TG, DTG, and DSC studies showed that three distinct thermal processes occurred in the fiber under heating at temperature from 37°C to 487°C. The first step took place in a temperature range from approximate 1737°C to 107°C due to a dehydration process. No decomposition of the fiber took place up to about 227°C. The second thermal process of the sample was under heating in the temperature above 227°C. Thermal decomposition led to incomplete carbonization of the fibers. The original structural features of the cellulosic were not completely lost in temperature above 227°C. The third thermal process was representative of combustion of the fibers to carbonized material.
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