In the literature, there are some kinetic studies of the me
thanolysis of fats and oils, of which only a few use palm oil. Freedman et al. [10] studied the butanolysis and the methanolysis of soybean oil. For the methanolysis with a 6:1 molar ratio of methanol to oil, 0.5 wt% of sodium methoxide as catalyst by oil weight and temperatures between 20 and 60 C, the experimental data fit better to a combination of second order consecutive and fourth order shunt reaction kinetic model. Energies of activation determined in the study ranged from 8 to 20 kcal gmol–1. Boocock et al. [11] discussed the results and the analysis done by Freedman [10], and explained the differences between butanolysis and methanolysis as the result of a two phase reaction in which methanolysis occurs only in the methanol phase, where the oil concentration is very low, and the reaction rate is limited by mass transfer
In the literature, there are some kinetic studies of the methanolysis of fats and oils, of which only a few use palm oil. Freedman et al. [10] studied the butanolysis and the methanolysis of soybean oil. For the methanolysis with a 6:1 molar ratio of methanol to oil, 0.5 wt% of sodium methoxide as catalyst by oil weight and temperatures between 20 and 60 C, the experimental data fit better to a combination of second order consecutive and fourth order shunt reaction kinetic model. Energies of activation determined in the study ranged from 8 to 20 kcal gmol–1. Boocock et al. [11] discussed the results and the analysis done by Freedman [10], and explained the differences between butanolysis and methanolysis as the result of a two phase reaction in which methanolysis occurs only in the methanol phase, where the oil concentration is very low, and the reaction rate is limited by mass transfer
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