Novel ruthenium(II),
RubpySS, osmium(II), OsbpySS, and cyclometalated iridium(III), IrbpySS,
bipyridyl complexes with long spacers between the surface-active groups and
the metal were developed to reduce the distance-dependent, nonradiative
quenching pathways by the gold surface.
Novel ruthenium(II),RubpySS, osmium(II), OsbpySS, and cyclometalated iridium(III), IrbpySS,bipyridyl complexes with long spacers between the surface-active groups andthe metal were developed to reduce the distance-dependent, nonradiativequenching pathways by the gold surface.
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