reduced graphene oxide (rGO), possesses abundant oxygenic groups introduced by an oxidization reaction, has been used as an active precursor for synthesizing the nanohybrids [16–18]. All those prepared methods availably prohibited the agglomeration of the SiO2 and graphene. However, a bottleneck is that the plenty of reactive sites of GO and modified SiO2 had been expended through chemical reactions, results of which leaded to that rubber chains could not covalently bind to the surface of the hybrids, con- sidered to be detrimental to the compatibility between the hybrids and the rubber. As a result, the surface chemistry of the prepared SiO2@rGO hybrids made the hybrids unsuitable for use as rubber reinforcement. Accordingly, developing a new preparation strategy surmounting the deficiency is highly desired. Furthermore, it is commonly admitted that the crucial importance of filler–rubber interaction has been recognized to control the dispersion of fillers, and finally influences the mechanical performance of polymer composites. Nevertheless, the knowledge of the further investiga- tion by which the filler–rubber interaction affects the reinforce- ment still remains a challenge.