On the first day of college, I woke up quite early, took a shower, had some nice breakfast and a chat with my host family, and then got ready as quickly as possible, in order to catch a bus that would take me to the college. The day before I actually already took the journey to my college and back, just so that I would not get lost on my first day - I highly recommend you do this, too, it reduces a lot of the stress that comes with having to go to a new college for the first time.