1. Dissolution and carbonation
Rainfall is acidic because atmospheric carbon dioxide dissolves in the rainwater producing weak carbonic acid. In unpolluted environments, the rainfall pH is around 5.6. Acid rain occurs when gases such as sulfur dioxide and nitrogen oxides are present in the atmosphere.
These oxides react in the rain water to produce stronger acids and can lower the pH to 4.0. Sulfur dioxide, SO2, comes from volcanic eruptions or from fossil fuels, can become sulfuric acid within rainwater, which can cause solution weathering to the rocks on which it falls.
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