The density increased whereas the molar volume decreases because varies sodium oxide concentration are 10 to 30 mol%.The optical absorption spectra of glasses were measured in the wavelength range of 200-2,500 nm.The intensity of all absorption bands increased with increasing Na2O.In addition, the luminescence properties of Eu3+ dope zinc lithium sodium borate glasses system were carried out using wavelength of 394 nm, the luminescence peaks around 578,590,613,651 and 699 nm were observed.