he working principle of the organic Rankine cycle is the same as that of the Rankine cycle: the working fluid is pumped to a boiler where it is evaporated, passed through an expansion device (turbine or other expander), and then through a condenser heat exchanger where it is finally re-condensed.
In the ideal cycle described by the engine's theoretical model, the expansion is isentropic and the evaporation and condensation processes are isobaric.
In any real cycle, the presence of irreversibilities lowers the cycle efficiency. Those irreversibilities mainly occur:[1]
During the expansion: Only a part of the energy recoverable from the pressure difference is transformed into useful work. The other part is converted into heat and is lost. The efficiency of the expander is defined by comparison with an isentropic expansion.
In the heat exchangers: The working fluid takes a long and sinuous path which ensures good heat exchange but causes pressure drops that lower the amount of power recoverable from the cycle. Likewise, the temperature difference between the heat source/sink and the working fluid generates exergy destruction and reduces the cycle performance.