Gas porosity is the formation of bubbles within the casting after it has cooled. This occurs because most liquid materials can hold a large amount of dissolved gas, but the solid form of the same material cannot, so the gas forms bubbles within the material as it cools.[6] Gas porosity may present itself on the surface of the casting as porosity or the pore may be trapped inside the metal,[7] which reduces strength in that vicinity. Nitrogen, oxygen and hydrogen are the most encountered gases in cases of gas porosity.[5] In aluminum castings, hydrogen is the only gas that dissolves in significant quantity, which can result in hydrogen gas porosity.[8] For casting that are a few kilograms in weight the pores are usually 0.01 to 0.5 mm (0.00039 to 0.01969 in) in size. In larger casting they can be up to a millimeter (0.040 in) in diameter.[7]
To prevent gas porosity the material may be melted in a vacuum, in an environment of low-solubility gases, such as argon[9] or carbon dioxide,[10] or under a flux that prevents contact with the air. To minimize gas solubility the superheat temperatures can be kept low. Turbulence from pouring the liquid metal into the mold can introduce gases, so the molds are often streamlined to minimize such turbulence. Other methods include vacuum degassing, gas flushing, or precipitation. Precipitation involves reacting the gas with another element to form a compound that will form a dross that floats to the top. For instance, oxygen can be removed from copper by adding phosphorus; aluminum or silicon can be added to steel to remove oxygen.[6] A third source consists of reactions of the molten metal with grease or other residues in the mould.
Hydrogen is normally produced by the reaction of the metal with humidity or residual moisture in the mold. Drying the mold can eliminate this source of hydrogen formation.[11]
Gas porosity can sometimes be difficult to distinguish from microshrinkage because microshrinkage cavities can contain gases as well. In general, microporosities will form if the casting is not properly risered or if a material with a wide solidification range is cast. If neither of these are the case then most likely the porosity is due to gas formation.[12]
Blowhole defect in a cast iron part.
Tiny gas bubbles are called porosities, but larger gas bubbles are called a blowholes[13] or blisters. Such defects can be caused by air entrained in the melt, steam or smoke from the casting sand, or other gasses from the melt or mold. (Vacuum holes caused by metal shrinkage (see above) may also be loosely referred to as 'blowholes'). Proper foundry practices, including melt preparation and mold design, can reduce the occurrence of these defects. Because they are often surrounded by a skin of sound metal, blowholes may be difficult to detect, requiring harmonic, ultrasonic, magnetic, or X-ray (i.e., industrial CT scanning) analysis.