The potential applications of non-linear optical materials in the emerging fields of photonic, fiber optic communications, frequency doubling and optical signal processing areas has attracted the atten- tion of scientists [1,2]. The efficient optical frequency conversion of NLO crystals is the key step in the development of laser sys- tems. These systems are of great importance as wide range tunable sources of coherent illumination in UV, vis and NIR spectral regions. Recent investigations focus on the design of a novel material that can reach second order optical processes, and have strong inter- action with the oscillating electric field of light [3]. Till now in the fields of non-linear optical materials much attention has been devoted towards the preparation and optimization of novel optical materials and also they have become more significant because of their function in various photonic devices. In order to identify new