High-porosity cement foams based on ternary blends of Portland cement, metakaolin and silica fumewere prepared by the pre-foaming method. The effects of ternary blends on the early-age properties,air-void structure and hardened state properties of cement foams were investigated. The effect of meta-kaolin and silica fume on stabilizing air-voids was observed, and the collapse of cement foams during thehardening process was avoided by addition of metakaolin. Moreover, the compressive strength of theprepared 91% high-porosity cement foams was enhanced by addition of metakaolin and silica fume.The compressive strength and thermal conductivity reached 0.74 MPa and 0.054 W/m K, respectively.However, metakaolin and silica fume had a negative impact on the workability of the cement foam.