The increasing diffusion of Hi-tech complex products has raised the attention of scientific community towards their End of Life treatment, both in terms of assuring an appropriate disposal, to avoid the dispersion of harmful substances, and with the aim of their exploitation as valuable sources of raw
materials. PCBs were subjected to an innovative integrated process based on product centric approach to recover all valuable materials, and mixed plastic associated is also treated to maximize the production of valuable liquids and gas, reaching percentages at the highest equal to 95%.