The application of SPE for extraction of the principal components from coffee samples provides a more environmentally sensitive alternative to liquid–liquid extraction, a relatively sensible and low-cost procedure compatible with many analytical methods. This work is included in a broader project to access important chemical composition profiles that, correlated with sensory analysis, should make it possible to build a database for identification of different coffee products and improve roasting process and develop new gourmet products. The final database will allow the most accurate calibration