The Eu2+ activated alkaline-earth orthosilicate phosphors are suitable for the phosphor converting white LED, because when excited by UV-LED they show broad emission band due to the 4f65d1→4f7 transition of Eu2+ coupled to the host lattice [4] and [5]. In general, the phosphors converting white LED are embedded in organic resins. However, there are several problems in this type of white LED, including the large difference of refractive index between phosphors and organic resins which will lead to high amount of scattering light, and the poor heat-resistance which will lead to the degradation of luminous intensity and the change of emission color. Therefore, the glass ceramic phosphors have been studied as a promising material due to its better heat-resistance than organic resins, available facility of production process, ease of formability, and low porosity compared with sintered ceramics [6]. YAG glass ceramic phosphors for white LED have been investigated [7], [8], [9], [10] and [11]. In the present work, we reported the preparation and spectral analysis of the UV-LED excitable green emitting Eu2+ activated glass ceramics containing Ba2Si3O8 nano-crystals.