In this study, the catalysts K2CO3 supported Kraft lignin activated carbon (K2CO3/KLC) were prepared
in situ by simply mixing K2CO3 with technical Kraft lignin (KL) and subsequently activating at 800 C
for 2 h under N2 flow. The precursor and catalysts were characterized by thermal gravity analysis
(TGA), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy
(XPS), scanning electron microscopy (SEM) and Brunauer–Emmett–Teller (BET) surface area.
The catalytic performance of prepared catalysts was evaluated by transesterification of rapeseed oil with
methanol. The effects of various parameters on biodiesel yield were investigated. The biodiesel yield of
99.6% was achieved by using the catalyst prepared by 0.6 of K2CO3/KL mass ratio and activation at
800 C, under the transesterification condition of 65 C, 2 h, methanol to rapeseed oil molar ratio of
15:1 and 3.0 wt.% catalyst (relative to the weight of rapeseed oil). The solid catalyst can be reused for
4 times and biodiesel yield remained over 82.1% for the fourth time.