A novel inorganic and organic mixture cations templated indium phosphate:
Synthesis and crystal structure
A novel mixture cations templated indium phosphates, Li(C2N2H10)[In2(HPO4)3(PO4)], has been synthesized
under mild hydrothermal conditions and characterized by elemental analysis and FT-IR spectrum.
The crystal structure of title compound was determined by single crystal X-ray diffraction data. It belongs
to monoclinic, space group P2/n with unit cell dimension a = 9.4692(13) Å, b = 9.1622(12) Å, c = 9.7063
(14) Å, b = 117.5620(10). Its structure is characterized as a three-dimensional open-framework with
8-membered ring channels along a axis, where the inorganic lithium cation and organic double-protonated
ethylenediamine cation are located and interact with the framework both electrostatically and via
hydrogen bonds of N–H O.
A novel inorganic and organic mixture cations templated indium phosphate:
Synthesis and crystal structure
A novel mixture cations templated indium phosphates, Li(C2N2H10)[In2(HPO4)3(PO4)], has been synthesized
under mild hydrothermal conditions and characterized by elemental analysis and FT-IR spectrum.
The crystal structure of title compound was determined by single crystal X-ray diffraction data. It belongs
to monoclinic, space group P2/n with unit cell dimension a = 9.4692(13) Å, b = 9.1622(12) Å, c = 9.7063
(14) Å, b = 117.5620(10). Its structure is characterized as a three-dimensional open-framework with
8-membered ring channels along a axis, where the inorganic lithium cation and organic double-protonated
ethylenediamine cation are located and interact with the framework both electrostatically and via
hydrogen bonds of N–H O.
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